Problem
In a space with spatial dimensions, how many translational degrees of freedom does a monatomic molecule have? Calculate per molecule and the molar .
Solution
In a -dimensional space a molecule can move along independent directions, so it has translational degrees of freedom: By the equipartition theorem each degree of freedom carries a mean energy , so the mean energy per molecule is The molar heat capacity at constant volume is : Curiously, in a monatomic gas has the same as a diatomic gas in (where between translations and rotations): what matters is only the total number of quadratic degrees of freedom.
Links
Topics: Kinetic theory of gases Concepts: Internal energy Skills: Analysis of limiting cases and sci-fi physics