Problem
Imagine a gas with . What would its characteristics be? How many quadratic degrees of freedom would it have, and what physical situation would it correspond to?
Solution
From the specific heats. Mayer’s relation requires . With we have , hence:
Degrees of freedom. By the equipartition theorem , so:
only two quadratic degrees of freedom.
Physical situation. This corresponds to a gas whose motion is confined to a plane (2D), for example molecules constrained to slide over a wall or a surface: only two translational directions contribute to the energy.
Adiabatic. The law would be steeper than that of a monatomic gas (): for the same compression, the pressure would rise more rapidly.
Links
Topics: Thermodynamics Concepts: Specific heat and heat capacity Skills: Analysis of limiting cases and science-fiction physics Objects: Ideal gas